Pseudomorphic Growth of a Single Element Quasiperiodic Ultrathin Film on a Quasicrystal Substrate

An ultrathin film with a periodic interlayer spacing was grown by the deposition of Cu atoms on thefivefold surface of the icosahedral Al70 Pd21 Mn9 quasicrystal. For coverages from 5 to 25 monolayers, a distinctive quasiperiodic low-energy electron diffraction pattern is observed. Scanning tunneling microscopy images show that the in-plane structure comprises rows having separations of S = 4.5 �0.2 �A and L = 7.3 0.3 A, whose ratio equals � =1.618... within experimental error. The sequences of such row separations form segments of terms of the Fibonacci sequence, indicative of the formation of a pseudomorphic Cu film

The Structure of Alkali Halide Dimers: A Critical Test of Ionic Models and New Ab Initio Results

In semiempirical ionic models a number of adjustable parameters have to be fitted to experimental data of either monomer molecules or crystals. This leads to strong correlations between these constants and prevents a unique test and a clear physical interpretation of the fit parameters. Moreover, it is not clear whether these constants remain unchanged when the model is applied to dimers or larger clusters. It is shown that these correlations can be substantially reduced when reliable information about dimers is available from experiments or ab initio calculations. Starting with Dunham coefficients of the monomer potential determined from microwave measurements, we have calculated the monomer to dimer bond expansion and the bond angle without any additional adjustable parameter. Assuming that the overlap repulsion between nearest neighbors remains unchanged, the bond expansion is mainly determined by the simple Coulomb repulsion between equally charged ions and depends only very little on the effective ion polarizabilities. Deviation of the bond angle from 90° sensitively tests the difference of effective polarizabilities of the two ions. A comparison with previously available data and new ab initio MP2 results presented here for the heavy‐atom containing dimers shows that bond angles can be modeled reasonably well with Seitz–Ruffa corrected Pauling polarizabilities while calculated bond expansions are much too long. This shows that changes of the overlap repulsion term must be considered for reliable predictions of the structure of dimers and larger clusters

Signatures from a merging galaxy cluster and its AGN population : LOFAR observations of Abell 1682

Reproduced with permission from Astronomy & Astrophysics. © 2019 ESOWe present LOFAR data from 110-180 MHz of the merging galaxy cluster Abell 1682, alongside archival optical, radio, and X-ray data. Our images of 6 arcsec in resolution at low frequencies reveal new structures associated with numerous radio galaxies in the cluster. At a resolution of 20 arcsec we see diffuse emission throughout the cluster over hundreds of kiloparsecs, indicating particle acceleration mechanisms are in play as a result of the cluster merger event and powerful active galactic nuclei. We show that a significant part of the cluster emission is from an old radio galaxy with very steep spectrum emission (having a spectral index of α < -2.5). Furthermore, we identify a new region of diffuse steep-spectrum emission (α < -1.1) as a candidate for a radio halo which is co-spatial with the centre of the cluster merger. We suggest its origin as a population of old and mildly relativistic electrons left over from radio galaxies throughout the cluster which have been re-accelerated to higher energies by shocks and turbulence induced by the cluster merger event. We also note the discovery of six new giant radio galaxies in the vicinity of Abell 1682.Peer reviewedFinal Accepted Versio

Discovery of spectral curvature in the shock downstream region: CIZA J2242.8+5301

Giant cluster radio relics are thought to form at shock fronts in the course of collisions between galaxy clusters. Via processes that are still poorly understood, these shocks accelerate or re-accelerate cosmic-ray electrons and might amplify magnetic fields. The best object to study this phenomenon is the galaxy cluster CIZA J2242.8+5301 as it shows the most undisturbed relic. By means of Giant Metrewave Radio Telescope (GMRT) and Westerbork Synthesis Radio Telescope (WSRT) data at seven frequencies spanning from 153 MHz to 2272 MHz, we study the synchrotron emission in this cluster. We aim at distinguishing between theoretical injection and acceleration models proposed for the formation of radio relics. We also study the head-tail radio sources to reveal the interplay between the merger and the cluster galaxies. We produced spectral index, curvature maps and radio colour-colour plots and compared our data with predictions from models. We present one of the deepest 153 MHz maps of a cluster ever produced, reaching a noise level of 1.5 mJy/beam. We derive integrated spectra for four relics in the cluster, discovering extremely steep spectrum diffuse emission concentrated in multiple patches. We find a possible radio phoenix embedded in the relic to the south of the cluster. The spectral index of the northern relic retains signs of steepening from the front towards the back of the shock also at the radio frequencies below 600 MHz. The spectral curvature in the same relic also increases in the downstream area. The data is consistent with the Komissarov-Gubanov injection models, meaning that the emission we observe is produced by a single burst of spectrally-aged accelerated radio electrons.Comment: 19 pages, 23 figures; accepted for publication in Astronomy and Astrophysics; Version with high resolution images: http://home.strw.leidenuniv.nl/~astroe/doc/CIZA_gmrt_wsrt_review.pd

Radio continuum observations of new radio halos and relics from the NVSS and WENSS surveys

Radio halos and relics are diffuse radio sources found in galaxy clusters showing significant substructure at X-ray wavelengths. These sources provide important information about non-thermal processes taking place in the ICM. Until now only a few dozen relics and halos are known, while models predict that a much larger number of these sources exist. In this paper we present the results of an extensive observing campaign to search for new diffuse radio sources in galaxy clusters. We discovered 6 new radio relics, including a probable double relic system, and 2 radio halos. In addition, we confirm the presence of diffuse radio emission in four galaxy clusters. By constructing a sample of 35 radio relics we find that relics are mostly found along the major axis of the X-ray emission from the ICM, while their orientation is perpendicular to this axis. This is consistent with the scenario that relics trace merger shock waves. The major and minor axis ratio distribution of the ICM for clusters with relics is also broader than that of the NORAS-REFLEX sample. We compared the X-ray luminosity and redshift distributions of clusters with relics to an X-ray selected sample from the NORAS and REFLEX surveys. We find tentative evidence for an increase of the cluster's relic fraction with X-ray luminosity and redshift. [abridged]Comment: 20 pages, 26 figures, accepted for publication in A\&A on July 14, 201

Deep LOFAR observations of the merging galaxy cluster CIZA J2242.8+5301

Previous studies have shown that CIZA J2242.8+5301 (the 'Sausage' cluster, z = 0.192) is a massive merging galaxy cluster that hosts a radio halo and multiple relics. In this paper, we present deep, high-fidelity, low-frequency images made with the LOw-Frequency Array (LOFAR) between 115.5 and 179 MHz. These images, with a noise of 140 μJy beam- 1 and a resolution of θbeam = 7.3 arcsec × 5.3 arcsec, are an order of magnitude more sensitive and five times higher resolution than previous low-frequency images of this cluster. We combined the LOFAR data with the existing Giant Metrewave Radio Telescope (GMRT) (153, 323, 608 MHz) and Westerbork Synthesis Radio Telescope (WSRT) (1.2, 1.4, 1.7, 2.3 GHz) data to study the spectral properties of the radio emission from the cluster. Assuming diffusive shock acceleration (DSA), we found Mach numbers of Mn=2.7{}_{-0.3}^{+0.6} and Ms=1.9_{-0.2}^{+0.3} for the northern and southern shocks. The derived Mach number for the northern shock requires an acceleration efficiency of several percent to accelerate electrons from the thermal pool, which is challenging for DSA. Using the radio data, we characterized the eastern relic as a shock wave propagating outwards with a Mach number of Me=2.4_{-0.3}^{+0.5}, which is in agreement with MeX=2.5{}_{-0.2}^{+0.6} that we derived from Suzaku data. The eastern shock is likely to be associated with the major cluster merger. The radio halo was measured with a flux of 346 ± 64 mJy at 145 MHz. Across the halo, we observed a spectral index that remains approximately constant (α ^{145 MHz-2.3 GHz}_{{across ˜ 1 Mpc}^2}=-1.01± 0.10) after the steepening in the post-shock region of the northern relic. This suggests a generation of post-shock turbulence that re-energies aged electrons

The local adsorption structure of benzene on Si(001)-(2 × 1): a photoelectron diffraction investigation

Scanned-energy mode C 1s photoelectron diffraction has been used to investigate the local adsorption geometry of benzene on Si(001) at saturation coverage and room temperature. The results show that two different local bonding geometries coexist, namely the 'standard butterfly' (SB) and 'tilted bridge' (TB) forms, with a composition of 58 ± 29% of the SB species. Detailed structural parameter values are presented for both species including Si–C bond lengths. On the basis of published measurements of the rate of conversion of the SB to the TB form on this surface, we estimate that the timescale of our experiment is sufficient for achieving equilibrium, and in this case our results indicate that the difference in the Gibbs free energy of adsorption, ΔG(TB)−ΔG(SB), is in the range −0.023 to +0.049 eV. We suggest, however, that the relative concentration of the two species may also be influenced by a combination of steric effects influencing the kinetics, and a sensitivity of the adsorption energies of the adsorbed SB and TB forms to the nature of the surrounding benzene molecules

Radio observations of the double-relic galaxy cluster Abell 1240

We present LOFAR 120 − 168 MHz images of the merging galaxy cluster Abell 1240 that hosts double radio relics. In combination with the GMRT 595 − 629 MHz and VLA 2 − 4 GHz data, we characterised the spectral and polarimetric properties of the radio emission. The spectral indices for the relics steepen from their outer edges towards the cluster centre and the electric field vectors are approximately perpendicular to the major axes of the relics. The results are consistent with the picture that these relics trace large-scale shocks propagating outwards during the merger. Assuming diffusive shock acceleration (DSA), we obtain shock Mach numbers of M = 2.4 and 2.3 for the northern and southern shocks, respectively. For M ≲ 3 shocks, a pre-existing population of mildly relativistic electrons is required to explain the brightness of the relics due to the high (> 10 per cent) particle acceleration efficiency required. However, for M ≳ 4 shocks the required efficiency is ≳ 1% and ≳ 0.5%, respectively, which is low enough for shock acceleration directly from the thermal pool. We used the fractional polarization to constrain the viewing angle to ≥ 53 ± 3° and ≥ 39 ± 5° for the northern and southern shocks, respectively. We found no evidence for diffuse emission in the cluster central region. If the halo spans the entire region between the relics (∼1.8 Mpc) our upper limit on the power is P1.4 GHz = (1.4 ± 0.6) × 1023 W Hz−1 which is approximately equal to the anticipated flux from a cluster of this mass. However, if the halo is smaller than this, our constraints on the power imply that the halo is underluminous

Quantification of depth of anesthesia by nonlinear time series analysis of brain electrical activity

We investigate several quantifiers of the electroencephalogram (EEG) signal with respect to their ability to indicate depth of anesthesia. For 17 patients anesthetized with Sevoflurane, three established measures (two spectral and one based on the bispectrum), as well as a phase space based nonlinear correlation index were computed from consecutive EEG epochs. In absence of an independent way to determine anesthesia depth, the standard was derived from measured blood plasma concentrations of the anesthetic via a pharmacokinetic/pharmacodynamic model for the estimated effective brain concentration of Sevoflurane. In most patients, the highest correlation is observed for the nonlinear correlation index D*. In contrast to spectral measures, D* is found to decrease monotonically with increasing (estimated) depth of anesthesia, even when a "burst-suppression" pattern occurs in the EEG. The findings show the potential for applications of concepts derived from the theory of nonlinear dynamics, even if little can be assumed about the process under investigation.Comment: 7 pages, 5 figure

Evaluation of the Illinois Soil Nitrogen Test in the North Central Region

Data from 96 locations across the North Central Region was complied to evaluate the usefulness of the Illinois soil nitrogen test (ISNT) in identifying fields where corn will not respond to additional N fertilizer and predicting the yield optimizing N rate (YONR) for each field. The ISNT could not accurately predict non-responsive sites, nor could it predict YONR. Sub-setting the data based on soil drainage class and previous crop did not improve the predictive capability of the ISNT. The ISNT was related to soil organic matter and was measuring a constant fraction of total soil N. The ISNT is not a meaningful tool upon which N rate decisions should be based